Transient and universal regimes in quantum reaction-transport kinetics have been investigated at the Max Planck Institute for the Physics of Complex Systems, Dresden, Germany. Quantum reaction-transport systems consist of coherently propagating particles which irreversibly react upon encounter. Relaxation is typically categorised as either reaction-limited or transport-limited, dependent on the relative timescales controlling reaction and particle transport. The established classification fails under specific conditions.
Accounting for non-equilibrium dynamics via Keldysh field theory and infrared divergence analysis
Keldysh field theory underpinned this investigation, representing the evolution of a system’s density and its probability distribution across time using forward and backward branches. It accounts for both coherent particle propagation and irreversible reactions within quantum reaction-transport systems, key for understanding how these processes interact at low dimensions. Introducing auxiliary fields and performing a mathematical transformation simplifying calculations, known as a Keldysh rotation, allowed detailed analysis of particle behaviour.
The framework enabled identification of infrared divergences, points where standard perturbative methods break down indicating that fluctuations become dominant over simple average behaviours like mean-field relaxation. Investigations focused on binary annihilation, specifically when two particles combine to disappear, to understand interactions between reactions and particle movement in lower dimensions.
The analysis revealed these divergences occur below an upper critical dimension of 2; this suggests conventional calculation approaches are no longer reliable due to strong fluctuation effects. Low dimensional systems were studied via the quantum binary annihilation process, A + A → Ø. Consequently, reaction processes acquire singular fluctuation corrections below the upper critical dimension Dc, resulting in fluctuations dominating asymptotic kinetics.
Quantum decay dynamics diverge from established theory in reduced dimensionality
Researchers at Max Planck Institute have refined our understanding of how quantum systems relax over time, but their work exposes a tension between established theoretical frameworks and behaviour observed in lower dimensions. Conventional models categorise relaxation as limited by either reaction speed or particle transport; however, this study demonstrates that such classifications falter below two spatial dimensions because fluctuations become overwhelmingly dominant. This challenges assumptions underpinning many existing calculations used to predict system evolution.
Investigation into these quantum reaction-transport systems reveals a fundamental shift in how particles relax as dimensionality decreases. Random fluctuations became the primary driver of system dynamics when confined to one dimension. These findings override expectations linked to mean-field relaxation and lead to an unexpected transport-limited regime where particle motion dictates decay rates even with minimal loss of particles. The results highlight limitations within current theoretical approaches for describing low dimensional kinetics.
The research demonstrated that random fluctuations, rather than simple average behaviours, control how quantum systems lose energy in lower dimensions. This means established methods used to predict the behaviour of such systems become unreliable below two spatial dimensions because they underestimate these fluctuation effects. Specifically, researchers found a transition towards transport-limited regimes in one dimension, characterised by particle number decreasing proportionally to the inverse square root of time. The authors also showed effective collisions between particles emerge from these same fluctuations, potentially leading to quasi-stationary thermal states in higher, but still limited, dimensions.
👉 More information
🗞 Transient and universal regimes in quantum reaction-transport kinetics
✍️ Hossein Hosseinabadi and Roderich Moessner
🧠 ArXiv: https://arxiv.org/abs/2609.09305




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