The superconducting transition temperature of iron selenide (FeSe) exhibited surprising behavior when researchers at the Hefei Institutes of Physical Science of the Chinese Academy of Sciences introduced zinc into its crystal structure. Rather than a simple decline, the temperature initially decreased, then increased, and finally decreased again with rising zinc concentration.
This non-monotonic response indicates that impurities and the material’s electronic structure compete in ways that defy expectations of weakened superconductivity. According to the researchers, these findings show that FeSe retains its two-gap superconducting state despite zinc doping, offering new insights into superconductivity in iron-based materials.
Zinc Doping Induces Non-Monotonic Superconducting Transition Temperatures in FeSe
The team’s work, published in Physical Review B, used the Steady High Magnetic Field Facility to probe the material’s properties. The introduction of zinc, a nonmagnetic element, caused local distortions and defects within the FeSe crystal structure, increasing electron scattering, yet the superconducting properties did not simply degrade as anticipated. Measurements of low-temperature specific heat provided further evidence supporting a two-gap superconducting state, a model where two distinct energy gaps govern the behavior of superconducting electrons.
The relative contributions of these two energy gaps remained largely unchanged even as the zinc concentration varied, suggesting that the scattering induced by zinc between different electronic bands is relatively weak. One gap exhibits an anisotropic extended s-wave structure, while the other is an isotropic s-wave gap, a specific arrangement of electron pairing. The team’s phase diagram, generated from magnetization, resistivity and specific-heat measurements, visually demonstrates this non-monotonic behavior of the critical temperature as a function of zinc concentration, providing a detailed map of the material’s superconducting properties under varying doping levels.




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