Revolutionizing Sensing: Quantum Technology Breaks Classical Limits

Quantum sensing, a revolutionary field that harnesses the genuine quantum properties of tiny physical quantities, has emerged as a game-changer in various scientific disciplines. By exploiting the unique characteristics of spins, researchers have been able to measure minuscule magnetic fields, temperatures, and other physical parameters with unprecedented sensitivity and precision.

Recent breakthroughs in molecular spin technology have shown that these tiny particles can be used as quantum sensors capable of probing magnetic fields down to the atomic scale limit. The development of novel sensing protocols, such as Dynamical Decoupling sequences, has further enhanced the sensitivity of these measurements, allowing for detection levels as low as 10^-9 THz^-1.

The applications of quantum sensing are vast and varied, ranging from photonics and nuclear spin resonance to medicine, materials science, and geophysics. The potential of molecular spins as quantum sensors is particularly exciting, with researchers exploring ways to integrate these tiny particles into hybrid quantum circuits and other technologies.

As the field continues to evolve, further research is needed to fully exploit the potential of quantum sensing and to develop practical applications in various fields. With its unparalleled sensitivity and precision, this technology has the power to revolutionize our understanding of magnetic fields and their applications, opening up new avenues for scientific discovery and innovation.

Quantum sensing, the exploitation of genuine quantum properties to probe tiny physical quantities, has emerged as a promising field with far-reaching implications. By leveraging the unique characteristics of quantum systems, researchers have been able to overcome fundamental limitations and outperform classical sensing methods.

In recent years, quantum sensing has been applied to measure a wide range of physical quantities, including electric or magnetic fields, temperature, pressure, rotation angle, speed, time frequency, and acceleration. This has led to innovative applications in photonics, nuclear and electron spin resonance, among others. Spins, being natural candidates for quantum sensing, have shown remarkable performances as sensors.

The nitrogen-vacancy (NV) center in diamonds, both as ensembles and single isolated spins, has demonstrated exceptional sensitivity as a quantum sensor. Sensitivities on the order of μTH z-1 have been reported for single NV centers using scanning probe microscopy tips, while typical values range from few units to tens of nTH z-1 for single spins using Optically Detected Magnetic Resonance (ODMR) protocols based on Dynamical Decoupling microwave sequences.

Using ensembles has the advantage of providing a parallel average of the response of N identical copies of single spins, as well as larger fluorescence signals to be measured in ODMR. However, increasing spin concentration reduces memory time, giving an upper bound for sensitivity that can only be overcome with specific and ad-hoc microwave decoupling schemes.

Molecular Spins: A New Player

Molecular spins have emerged as a promising new player in the field of quantum sensing. By exploiting their quantum nature through appropriate sensing protocols, researchers have been able to enlarge their applicability to fields not always accessible by classical sensors. In this context, molecular spin ensembles embedded into hybrid quantum circuits have shown great potential.

The first demonstration of quantum sensing protocols for AC magnetic fields with molecular spin ensembles has paved the way for the development of strategies to exploit molecular spins as quantum sensors. Using only echo detection at microwave frequency and no optical readout, Dynamical Decoupling protocols synchronized with the AC magnetic fields can enhance sensitivity up to S10-9TH z-1 with a low 45 number of applied pulses.

This breakthrough has significant implications for the development of new sensing technologies that can probe tiny physical quantities with unprecedented precision. The use of molecular spins as quantum sensors offers a promising avenue for overcoming fundamental limitations and outperforming classical sensing methods.

Dynamical Decoupling: A Key Enabler

Dynamical Decoupling (DD) protocols have emerged as a key enabler in the field of quantum sensing. By synchronizing DD sequences with AC magnetic fields, researchers have been able to enhance sensitivity and overcome fundamental limitations. The use of DD protocols has been shown to be particularly effective when combined with echo detection at microwave frequency and no optical readout.

The application of DD protocols has led to significant improvements in sensitivity, with values up to S10-9TH z-1 reported for molecular spin ensembles embedded into hybrid quantum circuits. This breakthrough has paved the way for the development of new sensing technologies that can probe tiny physical quantities with unprecedented precision.

Sensitivity: A Key Performance Metric

Sensitivity is a key performance metric in the field of quantum sensing. It measures the ability of a sensor to detect tiny physical quantities, and is typically expressed in units of TH z-1. The sensitivity of a sensor is influenced by various factors, including the type of spin used, the number of spins, and the protocol employed.

In the context of molecular spin ensembles embedded into hybrid quantum circuits, sensitivities up to S10-9TH z-1 have been reported using only echo detection at microwave frequency and no optical readout. This represents a significant improvement over classical sensing methods, and has important implications for the development of new sensing technologies.

Applications: A New Frontier

The applications of quantum sensing are vast and varied. By leveraging the unique characteristics of quantum systems, researchers have developed innovative solutions for a wide range of fields, including photonics, nuclear and electron spin resonance, and more.

In the context of molecular spin ensembles embedded into hybrid quantum circuits, the potential applications are particularly exciting. The ability to probe tiny physical quantities with unprecedented precision has significant implications for fields such as materials science, chemistry, and biology.

Conclusion

Quantum sensing has emerged as a promising new field with far-reaching implications. By leveraging the unique characteristics of quantum systems, researchers have been able to overcome fundamental limitations and outperform classical sensing methods. The use of molecular spins as quantum sensors offers a promising avenue for developing new sensing technologies that can probe tiny physical quantities with unprecedented precision.

The application of Dynamical Decoupling protocols has been shown to be particularly effective in enhancing sensitivity and overcoming fundamental limitations. Sensitivity is a key performance metric in the field of quantum sensing, and values up to S10-9TH z-1 have been reported for molecular spin ensembles embedded into hybrid quantum circuits.

As researchers continue to explore the potential of quantum sensing, new applications and technologies are likely to emerge. The future of this exciting field holds much promise, and is sure to be shaped by innovative research and development in the years to come.

Publication details: “Quantum sensing of magnetic fields with molecular spins”
Publication Date: 2024-04-23
Authors: Claudio Bonizzoni, Alberto Ghirri, Fabio Santanni, M. Affronte, et al.
Source: npj Quantum Information
DOI: https://doi.org/10.1038/s41534-024-00838-5

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